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  <cached-name>2-O-alpha-Mannosyl-D-glycerate Degradation</cached-name>
  <cached-description>2-O-α-Mannosyl-D-glycerate (MG; also named as Alpha-Mannosylglycerate) is an organic compound that will affect the osmosis in hyperthermophilic archaea and bacteria. In E.coli, 2-O-α-mannosyl-D-glycerate PTS permease (mngA) import MG into cell, and then phosphorylate MG to 2-O-(6-phospho-α-mannosyl)-D-glycerate by phosphocarrier protein HPr. 2-O-(6-phospho-α-mannosyl)-D-glycerate is converted to glyceric acid as well as mannose 6-phosphate by alpha-mannosidase mngB. Finally, glyceric acid is catalyzed to 2-Phospho-D-glyceric acid with ATP as energy source by Glycerate kinase 2.  E.coli can't use MG as osmotic stress protection, but it can use MG as a carbon source.</cached-description>
  <cached-subject>Metabolic</cached-subject>
  <pw-id>PW513788</pw-id>
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      <position>Center</position>
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        <background-color>#000099</background-color>
        <id>PathwayVisualization504270</id>
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          <id type="integer">514315</id>
          <name>2-O-alpha-Mannosyl-D-glycerate Degradation</name>
          <description>2-O-α-Mannosyl-D-glycerate (MG; also named as Alpha-Mannosylglycerate) is an organic compound that will affect the osmosis in hyperthermophilic archaea and bacteria. In E.coli, 2-O-α-mannosyl-D-glycerate PTS permease (mngA) import MG into cell, and then phosphorylate MG to 2-O-(6-phospho-α-mannosyl)-D-glycerate by phosphocarrier protein HPr. 2-O-(6-phospho-α-mannosyl)-D-glycerate is converted to glyceric acid as well as mannose 6-phosphate by alpha-mannosidase mngB. Finally, glyceric acid is catalyzed to 2-Phospho-D-glyceric acid with ATP as energy source by Glycerate kinase 2.  E.coli can't use MG as osmotic stress protection, but it can use MG as a carbon source.</description>
          <subject>Metabolic</subject>
          <species-id type="integer">2453</species-id>
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            <name>Cell</name>
            <ontology-id>CL:0000000</ontology-id>
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            <name>Hepatocyte</name>
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            <name>Cardiomyocyte</name>
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            <name>Neuron</name>
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            <name>Epithelial Cell</name>
            <ontology-id>CL:0000066</ontology-id>
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          <cell-type>
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            <name>Platelet </name>
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            <name>Beta cell</name>
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            <name>Astrocyte</name>
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            <name>Homo sapiens</name>
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            <classification>Eukaryote</classification>
            <common-name>Human</common-name>
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            <name>Bacteria</name>
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            <common-name>Bacteria</common-name>
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            <name>Escherichia coli</name>
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            <name>Mus musculus</name>
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            <classification>Eukaryote</classification>
            <common-name>Mouse</common-name>
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            <name>Bos taurus</name>
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            <common-name>Cattle</common-name>
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            <name>Rattus norvegicus</name>
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            <classification>Eukaryote</classification>
            <common-name>Rat</common-name>
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            <name>Schizosaccharomyces pombe</name>
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            <classification>Eukaryote</classification>
            <common-name></common-name>
          </species>
          <species>
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            <name>Solanum lycopersicum</name>
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            <classification>Eukaryote</classification>
            <common-name>Tomato</common-name>
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          <species>
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            <name>Arabidopsis thaliana</name>
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            <common-name>Thale cress</common-name>
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            <name>Saccharomyces cerevisiae</name>
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            <common-name>Yeast</common-name>
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            <name>Xenopus laevis</name>
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            <classification>Eukaryote</classification>
            <common-name>African clawed frog</common-name>
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            <name>Caenorhabditis elegans</name>
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            <common-name>Roundworm</common-name>
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            <name>Escherichia coli (strain K12)</name>
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            <classification>Prokaryote</classification>
            <common-name nil="true"/>
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            <name>Bathymodiolus platifrons</name>
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            <classification>Eukaryote</classification>
            <common-name>Deep sea mussel</common-name>
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            <name>Drosophila melanogaster</name>
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            <common-name>Fruit fly</common-name>
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            <name>Pseudomonas aeruginosa</name>
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            <common-name></common-name>
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            <name>Nitzschia sp.</name>
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          <species>
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            <name>Spathaspora passalidarum</name>
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            <name>Halococcus morrhuae DSM 1307</name>
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            <name>Cytoplasm</name>
            <ontology-id>GO:0005737</ontology-id>
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            <name>Mitochondrial Matrix</name>
            <ontology-id>GO:0005759</ontology-id>
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            <name>Mitochondrion</name>
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            <name>Cell Membrane</name>
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            <name>Endoplasmic Reticulum Body</name>
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            <name>2-O-(6-Phospho-α-mannosyl)-D-glycerate</name>
            <hmdb-id>HMDB0012152</hmdb-id>
            <description>2-O-(6-Phospho-alpha-mannosyl)-D-glycerate is an alpha-D-mannosylglycerate (MG) that is an intermediate in 2-O-alpha-mannosyl-D-glycerate degradation. It can be generated from 2-O-alpha-mannosyl-D-glycerate via the enzyme 2-O-alpha-mannosyl-D-glycerate transporting phosphotransferase system (mngA). 2-O-Alpha-mannosyl-D-glycerate is a natural extremolyte identified in microorganisms growing under extremely high temperatures up to 100 oC, and had been shown to protect proteins against various stress conditions such as heat, freezing, thawing, and drying. MG that is naturally occurring hyperthermophilic osmolytes, could be potential drug candidates or lead compounds against alpha,beta aggregation associated with Alzheimer's disease(PMID: 18304694). In most organisms MG is produced from guanosine pyrophosphate mannose (GDP-alpha-D-mannose) via mannosyl-3-phosphoglycerate in two steps, catalyzed by the enzymes mannosyl-3-phosphoglycerate synthase and mannosyl-3-phosphoglycerate phosphatase.</description>
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            <moldb-smiles>OC[C@@H](O[C@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H](O)[C@@H]1O)C(O)=O</moldb-smiles>
            <moldb-formula>C9H17O12P</moldb-formula>
            <moldb-inchi>InChI=1S/C9H17O12P/c10-1-3(8(14)15)20-9-7(13)6(12)5(11)4(21-9)2-19-22(16,17)18/h3-7,9-13H,1-2H2,(H,14,15)(H2,16,17,18)/t3-,4-,5-,6+,7+,9+/m1/s1</moldb-inchi>
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            <moldb-iupac>(2R)-3-hydroxy-2-{[(2R,3S,4S,5S,6R)-3,4,5-trihydroxy-6-[(phosphonooxy)methyl]oxan-2-yl]oxy}propanoic acid</moldb-iupac>
            <moldb-average-mass>348.1978</moldb-average-mass>
            <moldb-mono-mass>348.04576252</moldb-mono-mass>
            <moldb-alogps-logs>-1.09</moldb-alogps-logs>
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            <moldb-traditional-iupac>(2R)-3-hydroxy-2-{[(2R,3S,4S,5S,6R)-3,4,5-trihydroxy-6-[(phosphonooxy)methyl]oxan-2-yl]oxy}propanoic acid</moldb-traditional-iupac>
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            <synonyms>2-o-(6-phospho-a-mannosyl)-d-glycerate;2-o-(6-phospho-a-mannosyl)-d-glyceric acid;2-o-(6-phospho-alpha-mannosyl)-d-glyceric acid;2-o-(6-phospho-alpha-mannosyl)-delta-glycerate;2-o-(6-phospho-alpha-mannosyl)-delta-glyceric acid;2-o-(6-phospho-alpha-d-mannosyl)-d-glycerate;2-o-(6-phospho-a-d-mannosyl)-d-glycerate;2-o-(6-phospho-a-d-mannosyl)-d-glyceric acid;2-o-(6-phospho-alpha-d-mannosyl)-d-glyceric acid;2-o-(6-phospho-α-d-mannosyl)-d-glycerate;2-o-(6-phospho-α-d-mannosyl)-d-glyceric acid;2-o-(6-phospho-α-mannosyl)-d-glycerate;2-o-(6-phospho-α-mannosyl)-d-glyceric acid</synonyms>
            <pwc-id>PW_C007709</pwc-id>
            <short-name>2O6pDg</short-name>
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            <name>Water</name>
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            <description>Water is a chemical substance that is essential to all known forms of life. It appears colorless to the naked eye in small quantities, though it is actually slightly blue in color. It covers 71% of Earth's surface. Current estimates suggest that there are 1.4 billion cubic kilometers (330 million m3) of it available on Earth, and it exists in many forms. It appears mostly in the oceans (saltwater) and polar ice caps, but it is also present as clouds, rain water, rivers, freshwater aquifers, lakes, and sea ice. Water in these bodies perpetually moves through a cycle of evaporation, precipitation, and runoff to the sea. Clean water is essential to human life. In many parts of the world, it is in short supply. From a biological standpoint, water has many distinct properties that are critical for the proliferation of life that set it apart from other substances. It carries out this role by allowing organic compounds to react in ways that ultimately allow replication. All known forms of life depend on water. Water is vital both as a solvent in which many of the body's solutes dissolve and as an essential part of many metabolic processes within the body. Metabolism is the sum total of anabolism and catabolism. In anabolism, water is removed from molecules (through energy requiring enzymatic chemical reactions) in order to grow larger molecules (e.g. starches, triglycerides and proteins for storage of fuels and information). In catabolism, water is used to break bonds in order to generate smaller molecules (e.g. glucose, fatty acids and amino acids to be used for fuels for energy use or other purposes). Water is thus essential and central to these metabolic processes. Water is also central to photosynthesis and respiration. Photosynthetic cells use the sun's energy to split off water's hydrogen from oxygen. Hydrogen is combined with CO2 (absorbed from air or water) to form glucose and release oxygen. All living cells use such fuels and oxidize the hydrogen and carbon to capture the sun's energy and reform water and CO2 in the process (cellular respiration). Water is also central to acid-base neutrality and enzyme function. An acid, a hydrogen ion (H+, that is, a proton) donor, can be neutralized by a base, a proton acceptor such as hydroxide ion (OH-) to form water. Water is considered to be neutral, with a pH (the negative log of the hydrogen ion concentration) of 7. Acids have pH values less than 7 while bases have values greater than 7. Stomach acid (HCl) is useful to digestion. However, its corrosive effect on the esophagus during reflux can temporarily be neutralized by ingestion of a base such as aluminum hydroxide to produce the neutral molecules water and the salt aluminum chloride. Human biochemistry that involves enzymes usually performs optimally around a biologically neutral pH of 7.4. (Wikipedia).</description>
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            <drugbank-id nil="true"/>
            <moldb-smiles>O</moldb-smiles>
            <moldb-formula>H2O</moldb-formula>
            <moldb-inchi>InChI=1S/H2O/h1H2</moldb-inchi>
            <moldb-inchikey>XLYOFNOQVPJJNP-UHFFFAOYSA-N</moldb-inchikey>
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            <synonyms>Dihydrogen oxide;Steam;[oh2];Acqua;Agua;Aqua;Bound water;Dihydridooxygen;Eau;H2o;Hoh;Hydrogen hydroxide;Wasser</synonyms>
            <pwc-id>PW_C001420</pwc-id>
            <short-name>H2O</short-name>
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            <name>Mannose 6-phosphate</name>
            <hmdb-id>HMDB0001078</hmdb-id>
            <description>Mannose 6-phosphate, also known as alpha-D-mannose-6-p or man-6-p, belongs to the class of organic compounds known as hexose phosphates. These are carbohydrate derivatives containing a hexose substituted by one or more phosphate groups. Mannose 6-phosphate is soluble (in water) and a moderately acidic compound (based on its pKa). Mannose 6-phosphate has been found throughout most human tissues. Within the cell, mannose 6-phosphate is primarily located in the cytoplasm. In humans, mannose 6-phosphate is involved in the fructose and mannose degradation pathway and the fructose intolerance, hereditary pathway. Mannose 6-phosphate is also involved in the metabolic disorder called the fructosuria pathway. Mannose-6-phosphate is a potent competitive inhibitor of pinocytosis of human platelet beta-glucuronidase and it is a necessary component of the recognition marker on the enzyme for pinocytosis by human fibroblasts as well (PMID 908752).</description>
            <cas>3672-15-9</cas>
            <kegg-id>C00275</kegg-id>
            <pubchem-cid>439198</pubchem-cid>
            <chebi-id>49728</chebi-id>
            <biocyc-id>MANNOSE-6P</biocyc-id>
            <chemspider-id>388338</chemspider-id>
            <drugbank-id nil="true"/>
            <moldb-smiles>O[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H](O)[C@@H]1O</moldb-smiles>
            <moldb-formula>C6H13O9P</moldb-formula>
            <moldb-inchi>InChI=1S/C6H13O9P/c7-3-2(1-14-16(11,12)13)15-6(10)5(9)4(3)8/h2-10H,1H2,(H2,11,12,13)/t2-,3-,4+,5+,6-/m1/s1</moldb-inchi>
            <moldb-inchikey>NBSCHQHZLSJFNQ-RWOPYEJCSA-N</moldb-inchikey>
            <moldb-iupac>{[(2R,3S,4S,5S,6R)-3,4,5,6-tetrahydroxyoxan-2-yl]methoxy}phosphonic acid</moldb-iupac>
            <moldb-average-mass>260.1358</moldb-average-mass>
            <moldb-mono-mass>260.029718526</moldb-mono-mass>
            <moldb-alogps-logs>-0.92</moldb-alogps-logs>
            <moldb-donor-count>6</moldb-donor-count>
            <moldb-traditional-iupac>mannose 6 phosphate</moldb-traditional-iupac>
            <moldb-formal-charge type="integer">0</moldb-formal-charge>
            <moldb-physiological-charge type="integer">-2</moldb-physiological-charge>
            <drugbank-metabolite-id nil="true"/>
            <foodb-id>FDB022411</foodb-id>
            <synonyms>D-mannose 6-phosphate;Man-6-p;Mannose 6-phosphate;Mannose-6-phosphate;Alpha-d-mannose-6-p;Alpha-d-mannose-6-phosphate;Alpha-delta-mannose-6-p;Alpha-delta-mannose-6-phosphate;Delta-mannose 6-phosphate</synonyms>
            <pwc-id>PW_C000848</pwc-id>
            <short-name>Man-6P</short-name>
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                <id type="integer">1016</id>
                <biological-state-id type="integer">8</biological-state-id>
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                <id type="integer">13320</id>
                <biological-state-id type="integer">151</biological-state-id>
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                <id type="integer">77921</id>
                <biological-state-id type="integer">111</biological-state-id>
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                <id type="integer">120718</id>
                <biological-state-id type="integer">122</biological-state-id>
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                <id type="integer">123323</id>
                <biological-state-id type="integer">135</biological-state-id>
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            </element-states>
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            <id type="integer">90</id>
            <name>Glyceric acid</name>
            <hmdb-id>HMDB0000139</hmdb-id>
            <description>Glyceric acid is a colourless syrupy acid, obtained from oxidation of glycerol. It is a compound that is secreted excessively in the urine by patients suffering from D-glyceric aciduria, an inborn error of metabolism, and D-glycerate anemia. Deficiency of human glycerate kinase leads to D-glycerate acidemia/D-glyceric aciduria. Symptoms of the disease include progressive neurological impairment, hypotonia, seizures, failure to thrive, and metabolic acidosis. At sufficiently high levels, glyceric acid can act as an acidogen and a metabotoxin. An acidogen is an acidic compound that induces acidosis, which has multiple adverse effects on many organ systems. A metabotoxin is an endogenously produced metabolite that causes adverse health effects at chronically high levels. Glyceric acid is an organic acid. Abnormally high levels of organic acids in the blood (organic acidemia), urine (organic aciduria), the brain, and other tissues lead to general metabolic acidosis. Acidosis typically occurs when arterial pH falls below 7.35. In infants with acidosis, the initial symptoms include poor feeding, vomiting, loss of appetite, weak muscle tone (hypotonia), and lack of energy (lethargy). These can progress to heart abnormalities, seizures, coma, and possibly death. These are also the characteristic symptoms of untreated glyceric aciduria. Many affected children with organic acidemias experience intellectual disability or delayed development. In adults, acidosis or acidemia is characterized by headaches, confusion, feeling tired, tremors, sleepiness, and seizures.</description>
            <cas>473-81-4</cas>
            <kegg-id>C00258</kegg-id>
            <pubchem-cid>439194</pubchem-cid>
            <chebi-id>32398</chebi-id>
            <biocyc-id>2-PG</biocyc-id>
            <chemspider-id>388334</chemspider-id>
            <drugbank-id nil="true"/>
            <moldb-smiles>OC[C@@H](O)C(O)=O</moldb-smiles>
            <moldb-formula>C3H6O4</moldb-formula>
            <moldb-inchi>InChI=1S/C3H6O4/c4-1-2(5)3(6)7/h2,4-5H,1H2,(H,6,7)/t2-/m1/s1</moldb-inchi>
            <moldb-inchikey>RBNPOMFGQQGHHO-UWTATZPHSA-N</moldb-inchikey>
            <moldb-iupac>(2R)-2,3-dihydroxypropanoic acid</moldb-iupac>
            <moldb-average-mass>106.0773</moldb-average-mass>
            <moldb-mono-mass>106.02660868</moldb-mono-mass>
            <moldb-alogps-logs>0.78</moldb-alogps-logs>
            <moldb-donor-count>3</moldb-donor-count>
            <moldb-traditional-iupac>glycerate</moldb-traditional-iupac>
            <moldb-formal-charge type="integer">0</moldb-formal-charge>
            <moldb-physiological-charge type="integer">-1</moldb-physiological-charge>
            <drugbank-metabolite-id nil="true"/>
            <foodb-id>FDB012242</foodb-id>
            <synonyms>(r)-glycerate;D-glycerate;D-glyceric acid;Glycerate;Glyceric acid;A,b-hydroxypropionate;A,b-hydroxypropionic acid;Alpha,beta-hydroxypropionic acid;R-glyceric acid;Alpha,beta-hydroxypropionate;α,β-hydroxypropionate;α,β-hydroxypropionic acid;R-glycerate</synonyms>
            <pwc-id>PW_C000090</pwc-id>
            <short-name>Glycera</short-name>
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            <name>Adenosine triphosphate</name>
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            <description>Adenosine triphosphate (ATP) is a nucleotide consisting of a purine base (adenine) attached to the first carbon atom of ribose (a pentose sugar). Three phosphate groups are esterified at the fifth carbon atom of the ribose. ATP is incorporated into nucleic acids by polymerases in the processes of DNA replication and transcription. ATP contributes to cellular energy charge and participates in overall energy balance, maintaining cellular homeostasis. ATP can act as an extracellular signaling molecule via interactions with specific purinergic receptors to mediate a wide variety of processes as diverse as neurotransmission, inflammation, apoptosis, and bone remodelling. Extracellular ATP and its metabolite adenosine have also been shown to exert a variety of effects on nearly every cell type in human skin, and ATP seems to play a direct role in triggering skin inflammatory, regenerative, and fibrotic responses to mechanical injury, an indirect role in melanocyte proliferation and apoptosis, and a complex role in Langerhans cell-directed adaptive immunity. During exercise, intracellular homeostasis depends on the matching of adenosine triphosphate (ATP) supply and ATP demand. Metabolites play a useful role in communicating the extent of ATP demand to the metabolic supply pathways. Effects as different as proliferation or differentiation, chemotaxis, release of cytokines or lysosomal constituents, and generation of reactive oxygen or nitrogen species are elicited upon stimulation of blood cells with extracellular ATP. The increased concentration of adenosine triphosphate (ATP) in erythrocytes from patients with chronic renal failure (CRF) has been observed in many studies but the mechanism leading to these abnormalities still is controversial. (PMID: 15490415, 15129319, 14707763, 14696970, 11157473).</description>
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            <kegg-id>C00002</kegg-id>
            <pubchem-cid>5957</pubchem-cid>
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            <biocyc-id>ATP</biocyc-id>
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            <drugbank-id>DB00171</drugbank-id>
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            <moldb-alogps-logs>-2.05</moldb-alogps-logs>
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            <synonyms>5'-(tetrahydrogen triphosphate) adenosine;5'-atp;Atp;Adenosine 5'-triphosphate;Adenosine 5'-triphosphorate;Adenosine 5'-triphosphoric acid;Adenosine triphosphate;Adenylpyrophosphorate;Adenylpyrophosphoric acid;Adephos;Adetol;Adynol;Atipi;Atriphos;Cardenosine;Fosfobion;Glucobasin;Myotriphos;Phosphobion;Striadyne;Triadenyl;Triphosphaden;Triphosphoric acid adenosine ester;Adenosine-5'-triphosphate;H4atp;Adenosine triphosphoric acid;Adenosine-5'-triphosphoric acid</synonyms>
            <pwc-id>PW_C000414</pwc-id>
            <short-name>ATP</short-name>
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            <name>2-Phospho-D-glyceric acid</name>
            <hmdb-id>HMDB0003391</hmdb-id>
            <description>2-Phospho-D-glycerate or 2PG is an intermediate in gluconeogenesis. It is a glyceric acid which serves as the substrate in the ninth step of glycolysis. 2PG is converted by enolase into phosphoenolpyruvate (PEP), the penultimate step in the conversion of glucose to pyruvate. More specifically, 2PG can be generated from Glycerate-3-phosphate via phosphoglycerate mutase or from phosphoenolpyrvate via alpha enolase.</description>
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            <kegg-id>C00631</kegg-id>
            <pubchem-cid>439278</pubchem-cid>
            <chebi-id>17835</chebi-id>
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            <chemspider-id>388411</chemspider-id>
            <drugbank-id>DB01709</drugbank-id>
            <moldb-smiles>OC[C@@H](OP(O)(O)=O)C(O)=O</moldb-smiles>
            <moldb-formula>C3H7O7P</moldb-formula>
            <moldb-inchi>InChI=1S/C3H7O7P/c4-1-2(3(5)6)10-11(7,8)9/h2,4H,1H2,(H,5,6)(H2,7,8,9)/t2-/m1/s1</moldb-inchi>
            <moldb-inchikey>GXIURPTVHJPJLF-UWTATZPHSA-N</moldb-inchikey>
            <moldb-iupac>(2R)-3-hydroxy-2-(phosphonooxy)propanoic acid</moldb-iupac>
            <moldb-average-mass>186.0572</moldb-average-mass>
            <moldb-mono-mass>185.99293909</moldb-mono-mass>
            <moldb-alogps-logs>-0.96</moldb-alogps-logs>
            <moldb-donor-count>4</moldb-donor-count>
            <moldb-traditional-iupac>(+-)-2-phosphoglycerate</moldb-traditional-iupac>
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            <foodb-id>FDB001407</foodb-id>
            <synonyms>(2r)-3-hydroxy-2-(phosphonooxy)propanoate;(2r)-3-hydroxy-2-(phosphonooxy)propanoic acid;2-phospho-d-glycerate;2-phospho-d-glyceric acid;3-d-hydroxy-2-phosphonooxy-propanoate;3-d-hydroxy-2-phosphonooxy-propanoic acid;D-glycerate 2-phosphate;2-phospho-(r)-glycerate;D-glyceric acid 2-phosphoric acid;2-phospho-(r)-glyceric acid</synonyms>
            <pwc-id>PW_C001870</pwc-id>
            <short-name>2PDG</short-name>
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                <id type="integer">127418</id>
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            <name>Adenosine diphosphate</name>
            <hmdb-id>HMDB0001341</hmdb-id>
            <description>Adenosine diphosphate, abbreviated ADP, is a nucleotide. It is an ester of pyrophosphoric acid with the nucleotide adenine. ADP consists of the pyrophosphate group, the pentose sugar ribose, and the nucleobase adenine. ADP is the product of ATP dephosphorylation by ATPases. ADP is converted back to ATP by ATP synthases.</description>
            <cas>58-64-0</cas>
            <kegg-id>C00008</kegg-id>
            <pubchem-cid>6022</pubchem-cid>
            <chebi-id>16761</chebi-id>
            <biocyc-id>ADP</biocyc-id>
            <chemspider-id>5800</chemspider-id>
            <drugbank-id nil="true"/>
            <moldb-smiles>NC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O</moldb-smiles>
            <moldb-formula>C10H15N5O10P2</moldb-formula>
            <moldb-inchi>InChI=1S/C10H15N5O10P2/c11-8-5-9(13-2-12-8)15(3-14-5)10-7(17)6(16)4(24-10)1-23-27(21,22)25-26(18,19)20/h2-4,6-7,10,16-17H,1H2,(H,21,22)(H2,11,12,13)(H2,18,19,20)/t4-,6-,7-,10-/m1/s1</moldb-inchi>
            <moldb-inchikey>XTWYTFMLZFPYCI-KQYNXXCUSA-N</moldb-inchikey>
            <moldb-iupac>[({[(2R,3S,4R,5R)-5-(6-amino-9H-purin-9-yl)-3,4-dihydroxyoxolan-2-yl]methoxy}(hydroxy)phosphoryl)oxy]phosphonic acid</moldb-iupac>
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            <moldb-mono-mass>427.029414749</moldb-mono-mass>
            <moldb-alogps-logs>-2.12</moldb-alogps-logs>
            <moldb-donor-count>6</moldb-donor-count>
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            <foodb-id>FDB021817</foodb-id>
            <synonyms>Adp;Adenosindiphosphorsaeure;Adenosine 5'-pyrophosphate;Adenosine diphosphate;Adenosine pyrophosphate;Adenosine-5'-diphosphate;Adenosine-5-diphosphate;Adenosine-diphosphate;5'-adenylphosphoric acid;Adenosine 5'-diphosphate;H3adp;5'-adenylphosphate;Adenosine 5'-diphosphoric acid;Adenosine-5'-diphosphoric acid</synonyms>
            <pwc-id>PW_C001034</pwc-id>
            <short-name>ADP</short-name>
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            <name>2(α-D-Mannosyl)-D-glycerate</name>
            <hmdb-id nil="true"/>
            <description>2(&amp;alpha;-D-mannosyl)-D-glycerate; 2(alpha-D-Mannosyl)-D-glycerate; 2(alpha-D-Mannosyl)-D-glyceric acid; 2-(&amp;alpha;-D-mannopyranosyl)-D-glycerate; 2-(alpha-D-Mannopyranosyl)-D-glycerate; 2-(alpha-D-Mannopyranosyl)-D-glyceric acid; 2-O-alpha-Mannosyl-D-glycerate; 2-O-alpha-Mannosyl-D-glyceric acid; Alpha-Mannosylglycerate; Alpha-Mannosylglyceric acid; Mannosylglycerate; Mannosylglyceric acid</description>
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            <pubchem-cid>443262</pubchem-cid>
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            <moldb-smiles>[H][C@](CO)(O[C@@]1([H])O[C@]([H])(CO)[C@@]([H])(O)[C@]([H])(O)[C@]1([H])O)C(O)=O</moldb-smiles>
            <moldb-formula>C9H16O9</moldb-formula>
            <moldb-inchi>InChI=1S/C9H16O9/c10-1-3-5(12)6(13)7(14)9(17-3)18-4(2-11)8(15)16/h3-7,9-14H,1-2H2,(H,15,16)/t3-,4-,5-,6+,7+,9-/m1/s1</moldb-inchi>
            <moldb-inchikey>DDXCFDOPXBPUJC-SAYMMRJXSA-N</moldb-inchikey>
            <moldb-iupac>(2R)-3-hydroxy-2-{[(2R,3S,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}propanoic acid</moldb-iupac>
            <moldb-average-mass>268.2179</moldb-average-mass>
            <moldb-mono-mass>268.07943211</moldb-mono-mass>
            <moldb-alogps-logs>0.06</moldb-alogps-logs>
            <moldb-donor-count>6</moldb-donor-count>
            <moldb-traditional-iupac>(2R)-3-hydroxy-2-{[(2R,3S,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}propanoic acid</moldb-traditional-iupac>
            <moldb-formal-charge type="integer">0</moldb-formal-charge>
            <moldb-physiological-charge type="integer">-1</moldb-physiological-charge>
            <drugbank-metabolite-id nil="true"/>
            <foodb-id nil="true"/>
            <synonyms></synonyms>
            <pwc-id>PW_C041176</pwc-id>
            <short-name>2αDMDG</short-name>
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                <biological-state-id type="integer">107</biological-state-id>
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                <biological-state-id type="integer">318</biological-state-id>
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            </element-states>
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        </element-collections>
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            <name>Outer membrane lipoprotein carrier protein LolA</name>
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            <hmdbp-id nil="true"/>
            <gene-name>C448_13681</gene-name>
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          </protein>
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            <species-id type="integer">2453</species-id>
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            <gene-name>C448_09872</gene-name>
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            <drugbank-id nil="true"/>
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            <species-id type="integer">2453</species-id>
            <ec-numbers>3.5.3.8</ec-numbers>
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          </protein>
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            <name>Asn family transcriptional regulator</name>
            <uniprot-id>M0MLV5</uniprot-id>
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            <gene-name>C448_06955</gene-name>
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            <drugbank-id nil="true"/>
            <genbank-id nil="true"/>
            <species-id type="integer">2453</species-id>
            <ec-numbers></ec-numbers>
            <synonyms nil="true"/>
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          </protein>
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            <name>Unknown</name>
            <uniprot-id>Unknown</uniprot-id>
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            <gene-name nil="true"/>
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            <drugbank-id nil="true"/>
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            <species-id type="integer">2453</species-id>
            <ec-numbers>2.3.1.15</ec-numbers>
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                <biological-state-id type="integer">11529</biological-state-id>
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            </element-states>
          </protein>
        </proteins>
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          <protein-complex>
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            <name>α-mannosidase</name>
            <species-id type="integer">2453</species-id>
            <pwp-id>PW_P352900</pwp-id>
            <protein_complex-proteins>
              <protein-complex-protein>
                <id type="integer">380573</id>
                <protein-id type="integer">36149</protein-id>
                <stoichiometry type="integer">1</stoichiometry>
              </protein-complex-protein>
            </protein_complex-proteins>
          </protein-complex>
          <protein-complex>
            <id type="integer">131876</id>
            <name>glycerate kinase</name>
            <species-id type="integer">2453</species-id>
            <pwp-id>PW_P131876</pwp-id>
            <protein_complex-proteins>
              <protein-complex-protein>
                <id type="integer">146941</id>
                <protein-id type="integer">46669</protein-id>
                <stoichiometry type="integer" nil="true"/>
              </protein-complex-protein>
            </protein_complex-proteins>
          </protein-complex>
          <protein-complex>
            <id type="integer">54122</id>
            <name>HPr - phosphorylated</name>
            <species-id type="integer">2453</species-id>
            <pwp-id>PW_P054122</pwp-id>
            <protein_complex-proteins>
              <protein-complex-protein>
                <id type="integer">64854</id>
                <protein-id type="integer">27287</protein-id>
                <stoichiometry type="integer" nil="true"/>
              </protein-complex-protein>
            </protein_complex-proteins>
          </protein-complex>
          <protein-complex>
            <id type="integer">54123</id>
            <name>HPr</name>
            <species-id type="integer">2453</species-id>
            <pwp-id>PW_P054123</pwp-id>
            <protein_complex-proteins>
              <protein-complex-protein>
                <id type="integer">64855</id>
                <protein-id type="integer">27287</protein-id>
                <stoichiometry type="integer" nil="true"/>
              </protein-complex-protein>
            </protein_complex-proteins>
          </protein-complex>
          <protein-complex>
            <id type="integer">352901</id>
            <name>2-O-α-mannosyl-D-glycerate PTS permease</name>
            <species-id type="integer">2453</species-id>
            <pwp-id>PW_P352901</pwp-id>
            <protein_complex-proteins>
              <protein-complex-protein>
                <id type="integer">380574</id>
                <protein-id type="integer">92716</protein-id>
                <stoichiometry type="integer" nil="true"/>
              </protein-complex-protein>
            </protein_complex-proteins>
          </protein-complex>
        </protein-complexes>
        <reactions>
          <reaction>
            <id type="integer">1342217</id>
            <spontaneous type="boolean">false</spontaneous>
            <pwr-id>PW_R1342217</pwr-id>
            <direction>Right</direction>
            <reaction-left-elements>
              <reaction-left-element>
                <id type="integer">5806688</id>
                <element-id type="integer">7709</element-id>
                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-left-element>
              <reaction-left-element>
                <id type="integer">5806689</id>
                <element-id type="integer">1420</element-id>
                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-left-element>
            </reaction-left-elements>
            <reaction-right-elements>
              <reaction-right-element>
                <id type="integer">5806690</id>
                <element-id type="integer">848</element-id>
                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-right-element>
              <reaction-right-element>
                <id type="integer">5806691</id>
                <element-id type="integer">90</element-id>
                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-right-element>
            </reaction-right-elements>
            <reaction-enzymes>
              <reaction-enzyme>
                <id type="integer">1375549</id>
                <protein-complex-id type="integer">352900</protein-complex-id>
                <enzyme-class>3.2.1.170</enzyme-class>
              </reaction-enzyme>
            </reaction-enzymes>
          </reaction>
          <reaction>
            <id type="integer">1342218</id>
            <spontaneous type="boolean">false</spontaneous>
            <pwr-id>PW_R1342218</pwr-id>
            <direction>Right</direction>
            <reaction-left-elements>
              <reaction-left-element>
                <id type="integer">5806692</id>
                <element-id type="integer">90</element-id>
                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-left-element>
              <reaction-left-element>
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                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
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            </reaction-left-elements>
            <reaction-right-elements>
              <reaction-right-element>
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                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-right-element>
              <reaction-right-element>
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                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
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              <reaction-right-element>
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                <stoichiometry type="integer">1</stoichiometry>
                <element-type>Compound</element-type>
                <currency type="boolean">false</currency>
              </reaction-right-element>
            </reaction-right-elements>
            <reaction-enzymes>
              <reaction-enzyme>
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                <protein-complex-id type="integer">131876</protein-complex-id>
                <enzyme-class nil="true"/>
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            </reaction-enzymes>
          </reaction>
        </reactions>
        <reaction-coupled-transports>
          <reaction-coupled-transport>
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            <pwrct-id>PW_RCT031334</pwrct-id>
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