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hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI20 hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI21 hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI20 hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI21 hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI20 Thiamine biosynthetic bifunctional enzyme Thiamine biosynthetic bifunctional enzyme hydroxymethylpyrimidine/phosphomethylpyrimidine kinase THI20 acid phosphatase PHO12 Acid phosphatase PHO11 Repressible acid phosphatase acid phosphatase PHO3 Thiamine pyrophosphokinase ATP 4-amino-2- methyl-5- phosphomethylpyrimidine ADP 2-Methyl-4- amino-5- hydroxymethylpyrimidine diphosphate ATP 4-Amino-5- hydroxymethyl- 2- methylpyrimidine ADP pyrithiamine H2O 2-(2- methylpyridin- 3-yl)ethanol H+ 4-methyl-5-(2- phosphonooxyethyl)thiazole PPi Thiamine monophosphate 4-methyl-5-(β- hydroxyethyl)thiazole ATP H+ ADP oxythiamine H2O H+ 5- (hydroxymethyl)- 2-methyl-4(1H)- pyrimidinone H2O Thiamine Pi ATP H+ AMP Thiamine pyrophosphate oxidized electron acceptor reduced electron acceptor
THI20 THI21 THI20 THI21 THI20 THI6 THI6 THI20 PHO12 PHO11 PHO5 PHO3 THI80 ATP 4A2M5P ADP mahpdp ATP 4A5H2M ADP Pythi H2O mpetol H+ 4M52PT PPi TMP 4M5βHT ATP H+ ADP oxythi H2O H+ 5H2M41P H2O VitB1 Pi ATP H+ AMP ThiamPP ox-e red-e