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Malonyl-CoA minimal PKS chain-length factor (CLF/KS beta) Acyl carrier protein Ketosynthase Ketoreductase Aromatase/bifunctional aromatase (Cyclase/dehydratase) Act minimal PKS acyl carrier protein Act minimal PKS ketosynthase (KS/KS alpha) Ketoreductase OxyK Act minimal PKS ketosynthase (KS/KS alpha) Act minimal PKS chain-length factor (CLF/KS beta) Act minimal PKS acyl carrier protein Ketoreductase C7-C12 aromatase (ARO/CYC) Multifunctional cyclase- dehydratase- 3-O-methyl transferase TcmN Malonyl CoA-acyl carrier protein transacylase SnoaE Act minimal PKS chain-length factor (CLF/KS beta) 3,5,7,9,11,13,15- Heptaoxo- hexadecanoyl- [acp] 7,9,12- Octaketide intermediate 1 7,9,12- Octaketide intermediate 2 7,9,12- Octaketide intermediate 3 3,5,7,9,11,13,15,17,19- Nonaoxo-eicosanoyl-[acp] 7,9,12- Decaketide intermediate 1 7,9,12- Decaketide intermediate 2 7,9,12- Decaketide intermediate 3 Puruvate metabolism 8C02 + 8CoA NADPH + H+ <=>NADP+ 2 H2O 8 CO2 + 8 CoA NADPH + H+ <=>NADP+ 2 H2O 2 H2O Acyl-carrier protein H20 2 H2O
Malonyl-CoA oxyB acpP SLNWT_5121 SLINC_6892 DES30_1011443 DES30_1011423 DES30_1011421 SLINC_6892 oxyK DES30_1011421 DES30_1011422 DES30_1011423 SLINC_6892 mtmQ tcmN fenF snoaE DES30_1011422 3,5,7,9,11,13,15- Heptaoxo- hexadecanoyl- [acp] 7,9,12- Octaketide intermediate 1 7,9,12- Octaketide intermediate 2 7,9,12- Octaketide intermediate 3 3,5,7,9,11,13,15,17,19- Nonaoxo- eicosanoyl- [acp] 7,9,12- Decaketide intermediate 1 7,9,12- Decaketide intermediate 2 7,9,12- Decaketide intermediate 3 Puruvate metabolism
MalyCoA oxyB acpP SLNWT_5121 SLINC_6892 DES30_1011443 DES30_1011423 DES30_1011421 SLINC_6892 oxyK DES30_1011421 DES30_1011422 DES30_1011423 SLINC_6892 mtmQ tcmN fenF snoaE DES30_1011422 3579HHA 79OI1 79OI2 79OI3 3579NEA 79DI1 79DI2 79DI3 PW122266 8C02 + 8CoA NADPH + H+ <=>NADP+ 2 H2O 8 CO2 + 8 CoA NADPH + H+ <=>NADP+ 2 H2O 2 H2O Acyl-carrier protein H20 2 H2O
MalyCoA oxyB acpP SLNWT_5121 SLINC_6892 DES30_1011443 DES30_1011423 DES30_1011421 SLINC_6892 oxyK DES30_1011421 DES30_1011422 DES30_1011423 SLINC_6892 mtmQ tcmN fenF snoaE DES30_1011422 3579HHA 79OI1 79OI2 79OI3 3579NEA 79DI1 79DI2 79DI3 PW122266