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CHEBI:16015 ChEBI C5H11NO2 L-Valine 117.07898 2.0 30572 ChemSpider 6022 PubChem-compound HMDB02434 HMDB SMP00821 SMPDB HMDB00019 HMDB SMILES N[C@@H](CS)C(O)=O 937 ChemSpider CYS BioCyc 1.0 HMDB01341 HMDB ReactionCatalysis2655 ACTIVATION ReactionCatalysis2654 ACTIVATION ReactionCatalysis2657 ACTIVATION ReactionCatalysis2656 ACTIVATION Uncharacterized aminotransferase yfbQ SMILES O 50 ChemSpider ReactionCatalysis2653 ACTIVATION P0A6J8 UniProt HMDB00148 HMDB Branched-chain-amino-acid aminotransferase Alanine racemase, biosynthetic glutamate-pyruvate aminotransferase ATP BioCyc C3H7NO2 D-Alanine 89.047676 CHEBI:17594 ChEBI Cysteine desulfurase P09053 UniProt H4N Ammonium 18.034374 1.0 1.0 64234 ChemSpider 48 ChemSpider 51 PubChem-compound Pyruvic acid ADP BioCyc C3H4O3 Pyruvic acid 88.016045 P0A6J5 UniProt 2.0 6287 PubChem-compound D-alanine--D-alanine ligase B 1.0 D-Alanine 5742 ChemSpider CHEBI:17561 ChEBI 759-05-7 CAS cysteine desulfurase D-amino acid dehydrogenase Valine Transaminase C5H6O5 Oxoglutaric acid 146.02153 C5H8O3 Alpha-ketoisovaleric acid 116.04734 HMDB00243 HMDB L-Valine 1.0 5735 ChemSpider O4P Phosphate 94.95342 D-alanine--D-alanine ligase A C6H12N2O3 D-Alanyl-D-alanine 160.0848 5862 PubChem-compound 4650 PubChem-compound Alanine racemase, catabolic D-amino acid dehydrogenase small subunit HMDB41827 HMDB 2-KETO-ISOVALERATE BioCyc 1.0 HMDB00574 HMDB Valine--pyruvate aminotransferase Ammonium SubPathwayInteraction1525 SubPathway1525Reaction SubPathwayReaction SubPathwayInteraction1524 SubPathway1524Reaction SubPathwayReaction PW000785 PathWhiz CHEBI:16977 ChEBI P07862 UniProt 236-TRICHLOROHYDROQUINONE BioCyc C00472 KEGG Compound SubPathwayInteraction1523 SubPathwayReaction SubPathway1523Reaction SubPathwayInteraction1522 SubPathway1522Reaction SubPathwayReaction 218 ChemSpider Adenosine triphosphate L-Glutamic acid Quinone SMILES [O-]P([O-])([O-])=O SMILES OC(=O)CCC(=O)C(O)=O SMILES CC(C)C(=O)C(O)=O HMDB00208 HMDB CHEBI:30915 ChEBI an [L-cysteine desulfurase] L-cysteine persulfide D-ALANINE BioCyc C00009 KEGG Compound HMDB01310 HMDB C00008 KEGG Compound 2.0 L-ALPHA-ALANINE BioCyc SMILES C[C@@H](N)C(=O)N[C@H](C)C(O)=O C00001 KEGG Compound Uncharacterized aminotransferase yfbQ 56-41-7 CAS 1.0 CHEBI:18367 ChEBI 1032 ChemSpider C00002 KEGG Compound 1031 ChemSpider 6050 ChemSpider 1.0 HMDB01429 HMDB GLT BioCyc 49 PubChem-compound SMP00924 SMPDB Alanine racemase, biosynthetic Cysteine desulfurase C00133 KEGG Compound C01342 KEGG Compound SMILES C[C@H](N)C(O)=O CHEBI:28938 ChEBI 5950 PubChem-compound SMP00807 SMPDB 5957 PubChem-compound L-alanine metabolism SMP00810 SMPDB SMP00811 SMPDB C00022 KEGG Compound 56-65-5 CAS C00141 KEGG Compound 5653 ChemSpider 338-69-2 CAS C00026 KEGG Compound C00025 KEGG Compound 4573916 ChemSpider Adenosine diphosphate D-alanine ligase L-alanine racemase C10H15N5O10P2 Adenosine diphosphate 427.02942 1.0 CHEBI:16414 ChEBI D-amino acid dehydrogenase small subunit C6H6O2 Hydroquinone 110.03678 D-alanine--D-alanine ligase A 52-90-4 CAS CPD-8587 BioCyc CHEBI:16530 ChEBI HMDB03364 HMDB 328-50-7 CAS Water C00041 KEGG Compound Uncharacterized aminotransferase yfdZ P0AB80 UniProt 1.0 5460362 PubChem-compound P0A6B4 UniProt P0A6B7 UniProt CHEBI:15570 ChEBI L-Cysteine SMILES NC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O 764 ChemSpider 14798-03-9 CAS 2.0 HMDB00538 HMDB 1.0 CHEBI:15422 ChEBI 785 PubChem-compound 1.0 7732-18-5 CAS SMILES CC(C)[C@H](N)C(O)=O 72-18-4 CAS 127-17-3 CAS C00183 KEGG Compound C6H4O2 Quinone 108.021126 56-86-0 CAS CHEBI:16509 ChEBI 6.0 C5H9NO4 L-Glutamic acid 147.05316 33032 PubChem-compound SMILES [NH4+] HMDB00883 HMDB C10H16N5O13P3 Adenosine triphosphate 506.99576 4489 ChemSpider SMILES C[C@@H](N)C(O)=O glycolysis and pyruvate dehydrogenase SubPathway cysteine biosynthesis SubPathway peptidoglycan biosynthesis I SubPathway L-glutamate metabolism SubPathway 1.0 CPD-8130 BioCyc Hydroquinone CHEBI:16761 ChEBI SMILES CC(=O)C(O)=O 71080 PubChem-compound 123-31-9 CAS 6.3.2.4 false 6.3.2.4 Adenosine triphosphate + 2 D-Alanine → Adenosine diphosphate + D-Alanyl-D-alanine + Phosphate LEFT_TO_RIGHT PW000789 PathWhiz PW000788 PathWhiz 5.1.1.1 false 5.1.1.1 L-Alanine ↔ D-Alanine REVERSIBLE 923-16-0 CAS CHEBI:16576 ChEBI 962 PubChem-compound P29012 UniProt C3H7NO2 L-Alanine 89.047676 2-KETOGLUTARATE BioCyc 5800 ChemSpider D-Alanyl-D-alanine Branched-chain-amino-acid aminotransferase Phosphate C00993 KEGG Compound 1.0 HMDB02111 HMDB 2.8.1.7 false 2.8.1.7 L-Cysteine + an [L-cysteine desulfurase] L-cysteine persulfide → L-Alanine + an [L-cysteine desulfurase] L-cysteine persulfide LEFT_TO_RIGHT 2.6.1.66 false 2.6.1.66 L-Valine + Pyruvic acid → Alpha-ketoisovaleric acid + L-Alanine LEFT_TO_RIGHT 2.6.1.2 false 2.6.1.2 L-Glutamic acid + Pyruvic acid → L-Alanine + Oxoglutaric acid LEFT_TO_RIGHT 1.0 Oxoglutaric acid Alpha-ketoisovaleric acid SMILES O=C1C=CC(=O)C=C1 CHEBI:32816 ChEBI SMILES N[C@@H](CCC(O)=O)C(O)=O 2.6.1.42 false 2.6.1.42 Alpha-ketoisovaleric acid + L-Glutamic acid → L-Valine + Oxoglutaric acid LEFT_TO_RIGHT 1.4.99.1 false 1.4.99.1 D-Alanine + Quinone + Water → Ammonium + Hydroquinone + Pyruvic acid LEFT_TO_RIGHT CHEBI:15377 ChEBI 14265-44-2 CAS PYRUVATE BioCyc HMDB03459 HMDB 58-64-0 CAS SMILES NC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(=O)OP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O Uncharacterized aminotransferase yfdZ D-alanine--D-alanine ligase B VAL BioCyc 1.0 1.0 SMILES OC1=CC=C(O)C=C1 PW000800 PathWhiz C3H7NO2S L-Cysteine 121.01975 16741146 PubChem-compound C00097 KEGG Compound C00530 KEGG Compound ReactionCatalysis2479 ACTIVATION H2O Water 18.010565 P77434 UniProt 1060 PubChem-compound 1061 PubChem-compound ReactionCatalysis2480 ACTIVATION L-Alanine 106-51-4 CAS 2.0 HMDB00161 HMDB D-ALA-D-ALA BioCyc Valine--pyruvate aminotransferase Alanine racemase, catabolic PW000906 PathWhiz P0A959 UniProt an [L-cysteine desulfurase] L-cysteine persulfide Alanine racemase, catabolic Alanine racemase, biosynthetic D-alanine--D- alanine ligase B D-alanine--D- alanine ligase A Uncharacterized aminotransferase yfdZ Uncharacterized aminotransferase yfbQ Valine-- pyruvate aminotransferase Branched- chain-amino- acid aminotransferase D-amino acid dehydrogenase small subunit Cysteine desulfurase L-Alanine D-Alanine D-Alanine ATP D-Alanyl-D- alanine ADP P i Pyruvic acid L-Glutamic acid Oxoglutaric acid L-Valine Pyruvic acid Alpha- ketoisovaleric acid Alpha- ketoisovaleric acid L-Glutamic acid Oxoglutaric acid H 2 O Quinone Ammonium Pyruvic acid Hydroquinone L-Cysteine L-Alanine an [L-cysteine desulfurase] L-cysteine persulfide an [L-cysteine desulfurase] L-cysteine persulfide cysteine biosynthesis glycolysis and pyruvate dehydrogenase L-glutamate metabolism glycolysis and pyruvate dehydrogenase peptidoglycan biosynthesis I
CHEBI:16015 ChEBI C5H11NO2 L-Valine 117.07898 2.0 30572 ChemSpider 6022 PubChem-compound HMDB02434 HMDB http://identifiers.org/smpdb/SMP00821 SMPDB HMDB00019 HMDB SMILES N[C@@H](CS)C(O)=O 937 ChemSpider CYS BioCyc 1.0 HMDB01341 HMDB ReactionCatalysis2655 ACTIVATION ReactionCatalysis2654 ACTIVATION ReactionCatalysis2657 ACTIVATION ReactionCatalysis2656 ACTIVATION Uncharacterized aminotransferase yfbQ SMILES O 50 ChemSpider ReactionCatalysis2653 ACTIVATION P0A6J8 UniProt HMDB00148 HMDB Branched-chain-amino-acid aminotransferase Alanine racemase, biosynthetic glutamate-pyruvate aminotransferase ATP BioCyc C3H7NO2 D-Alanine 89.047676 CHEBI:17594 ChEBI Cysteine desulfurase P09053 UniProt H4N Ammonium 18.034374 1.0 1.0 64234 ChemSpider 48 ChemSpider 51 PubChem-compound Pyruvic acid ADP BioCyc C3H4O3 Pyruvic acid 88.016045 P0A6J5 UniProt 2.0 6287 PubChem-compound D-alanine--D-alanine ligase B 1.0 D-Alanine 5742 ChemSpider CHEBI:17561 ChEBI 759-05-7 CAS cysteine desulfurase D-amino acid dehydrogenase Valine Transaminase C5H6O5 Oxoglutaric acid 146.02153 C5H8O3 Alpha-ketoisovaleric acid 116.04734 HMDB00243 HMDB L-glutamate metabolism SubPathway L-Valine 1.0 5735 ChemSpider O4P Phosphate 94.95342 D-alanine--D-alanine ligase A C6H12N2O3 D-Alanyl-D-alanine 160.0848 5862 PubChem-compound 4650 PubChem-compound Alanine racemase, catabolic D-amino acid dehydrogenase small subunit HMDB41827 HMDB 2-KETO-ISOVALERATE BioCyc 1.0 glycolysis and pyruvate dehydrogenase SubPathway HMDB00574 HMDB Valine--pyruvate aminotransferase Ammonium SubPathwayInteraction1525 SubPathway1525Reaction SubPathwayReaction SubPathwayInteraction1524 SubPathway1524Reaction SubPathwayReaction PW000785 PathWhiz CHEBI:16977 ChEBI P07862 UniProt 236-TRICHLOROHYDROQUINONE BioCyc C00472 KEGG Compound SubPathwayInteraction1523 SubPathwayReaction SubPathway1523Reaction SubPathwayInteraction1522 SubPathway1522Reaction SubPathwayReaction 218 ChemSpider Adenosine triphosphate L-Glutamic acid Quinone SMILES [O-]P([O-])([O-])=O SMILES OC(=O)CCC(=O)C(O)=O SMILES CC(C)C(=O)C(O)=O HMDB00208 HMDB CHEBI:30915 ChEBI an [L-cysteine desulfurase] L-cysteine persulfide D-ALANINE BioCyc C00009 KEGG Compound HMDB01310 HMDB C00008 KEGG Compound 2.0 L-ALPHA-ALANINE BioCyc SMILES C[C@@H](N)C(=O)N[C@H](C)C(O)=O C00001 KEGG Compound Uncharacterized aminotransferase yfbQ 56-41-7 CAS 1.0 CHEBI:18367 ChEBI 1032 ChemSpider C00002 KEGG Compound 1031 ChemSpider 6050 ChemSpider 1.0 HMDB01429 HMDB GLT BioCyc 49 PubChem-compound http://identifiers.org/smpdb/SMP00924 SMPDB Alanine racemase, biosynthetic Cysteine desulfurase C00133 KEGG Compound C01342 KEGG Compound SMILES C[C@H](N)C(O)=O CHEBI:28938 ChEBI 5950 PubChem-compound http://identifiers.org/smpdb/SMP00807 SMPDB 5957 PubChem-compound L-alanine metabolism http://identifiers.org/smpdb/SMP00810 SMPDB http://identifiers.org/smpdb/SMP00811 SMPDB C00022 KEGG Compound 56-65-5 CAS C00141 KEGG Compound 5653 ChemSpider 338-69-2 CAS C00026 KEGG Compound C00025 KEGG Compound 4573916 ChemSpider Adenosine diphosphate D-alanine ligase L-alanine racemase C10H15N5O10P2 Adenosine diphosphate 427.02942 1.0 CHEBI:16414 ChEBI D-amino acid dehydrogenase small subunit C6H6O2 Hydroquinone 110.03678 D-alanine--D-alanine ligase A 52-90-4 CAS CPD-8587 BioCyc CHEBI:16530 ChEBI HMDB03364 HMDB 328-50-7 CAS Water C00041 KEGG Compound Uncharacterized aminotransferase yfdZ P0AB80 UniProt 1.0 5460362 PubChem-compound cysteine biosynthesis SubPathway P0A6B4 UniProt P0A6B7 UniProt CHEBI:15570 ChEBI L-Cysteine SMILES NC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O 764 ChemSpider 14798-03-9 CAS 2.0 HMDB00538 HMDB 1.0 CHEBI:15422 ChEBI 785 PubChem-compound 1.0 7732-18-5 CAS SMILES CC(C)[C@H](N)C(O)=O 72-18-4 CAS 127-17-3 CAS C00183 KEGG Compound C6H4O2 Quinone 108.021126 56-86-0 CAS CHEBI:16509 ChEBI 6.0 C5H9NO4 L-Glutamic acid 147.05316 33032 PubChem-compound SMILES [NH4+] HMDB00883 HMDB C10H16N5O13P3 Adenosine triphosphate 506.99576 4489 ChemSpider SMILES C[C@@H](N)C(O)=O 1.0 CPD-8130 BioCyc Hydroquinone CHEBI:16761 ChEBI SMILES CC(=O)C(O)=O 71080 PubChem-compound 123-31-9 CAS 6.3.2.4 false 6.3.2.4 Adenosine triphosphate + 2 D-Alanine → Adenosine diphosphate + D-Alanyl-D-alanine + Phosphate LEFT_TO_RIGHT PW000789 PathWhiz PW000788 PathWhiz 5.1.1.1 false 5.1.1.1 L-Alanine ↔ D-Alanine REVERSIBLE 923-16-0 CAS CHEBI:16576 ChEBI 962 PubChem-compound P29012 UniProt C3H7NO2 L-Alanine 89.047676 2-KETOGLUTARATE BioCyc 5800 ChemSpider D-Alanyl-D-alanine Branched-chain-amino-acid aminotransferase Phosphate C00993 KEGG Compound 1.0 HMDB02111 HMDB 2.8.1.7 false 2.8.1.7 L-Cysteine + an [L-cysteine desulfurase] L-cysteine persulfide → L-Alanine + an [L-cysteine desulfurase] L-cysteine persulfide LEFT_TO_RIGHT 2.6.1.66 false 2.6.1.66 L-Valine + Pyruvic acid → Alpha-ketoisovaleric acid + L-Alanine LEFT_TO_RIGHT 2.6.1.2 false 2.6.1.2 L-Glutamic acid + Pyruvic acid → L-Alanine + Oxoglutaric acid LEFT_TO_RIGHT 1.0 Oxoglutaric acid Alpha-ketoisovaleric acid SMILES O=C1C=CC(=O)C=C1 CHEBI:32816 ChEBI SMILES N[C@@H](CCC(O)=O)C(O)=O 2.6.1.42 false 2.6.1.42 Alpha-ketoisovaleric acid + L-Glutamic acid → L-Valine + Oxoglutaric acid LEFT_TO_RIGHT 1.4.99.1 false 1.4.99.1 D-Alanine + Quinone + Water → Ammonium + Hydroquinone + Pyruvic acid LEFT_TO_RIGHT CHEBI:15377 ChEBI 14265-44-2 CAS PYRUVATE BioCyc HMDB03459 HMDB 58-64-0 CAS SMILES NC1=NC=NC2=C1N=CN2[C@@H]1O[C@H](COP(O)(=O)OP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O Uncharacterized aminotransferase yfdZ D-alanine--D-alanine ligase B VAL BioCyc 1.0 1.0 SMILES OC1=CC=C(O)C=C1 PW000800 PathWhiz C3H7NO2S L-Cysteine 121.01975 16741146 PubChem-compound C00097 KEGG Compound C00530 KEGG Compound ReactionCatalysis2479 ACTIVATION H2O Water 18.010565 P77434 UniProt 1060 PubChem-compound 1061 PubChem-compound ReactionCatalysis2480 ACTIVATION L-Alanine peptidoglycan biosynthesis I SubPathway 106-51-4 CAS 2.0 HMDB00161 HMDB D-ALA-D-ALA BioCyc Valine--pyruvate aminotransferase Alanine racemase, catabolic PW000906 PathWhiz P0A959 UniProt an [L-cysteine desulfurase] L-cysteine persulfide dadX alr ddlB ddlA yfdZ yfbQ avtA ilvE dadA iscS L-Alanine D-Alanine D-Alanine Adenosine triphosphate D-Alanyl-D- alanine Adenosine diphosphate Phosphate Pyruvic acid L-Glutamic acid Oxoglutaric acid L-Valine Pyruvic acid Alpha- ketoisovaleric acid Alpha- ketoisovaleric acid L-Glutamic acid Oxoglutaric acid Water Quinone Ammonium Pyruvic acid Hydroquinone L-Cysteine L-Alanine an [L-cysteine desulfurase] L-cysteine persulfide an [L-cysteine desulfurase] L-cysteine persulfide cysteine biosynthesis glycolysis and pyruvate dehydrogenase L-glutamate metabolism glycolysis and pyruvate dehydrogenase peptidoglycan biosynthesis I