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Aspartate 1-decarboxylase 3-methyl-2- oxobutanoate hydroxymethyltransferase 2- dehydropantoate 2-reductase Pantothenate synthetase Pantothenate kinase Coenzyme A biosynthesis bifunctional protein coaBC Coenzyme A biosynthesis bifunctional protein coaBC Phosphopantetheine adenylyltransferase Dephospho-CoA kinase 2-(5''- triphosphoribosyl)- 3'- dephosphocoenzyme- A synthase Dihydroxy-acid dehydratase L-Aspartic acid H + CO 2 β-alanine α- Ketoisovaleric acid 5,10- Methylene-THF H 2 O Tetrahydrofolic acid 2- dehydropantoate NADPH H + NADP (R)-pantoate β-Alanine ATP AMP PP i H + Pantothenic acid ATP ADP H + D-4'- Phosphopantothenate Cytidine triphosphate L-Cysteine Cytidine monophosphate PP i H + 4'- Phosphopantothenoylcysteine H + CO 2 4'- phosphopantetheine ATP H + PP i Dephospho-CoA ATP H + ADP Coenzyme A ATP H + Adenine 2'-(5- Triphosphoribosyl)- 3'-dephospho- CoA 2,3- Dihydroxyisovaleric acid H 2 O Valine Biosynthesis Aspartate Metabolism Ketol-acid reductoisomerase
panD panB panE panC coaA coaBC coaBC coaD coaE citG ilvD L-Aspartic acid Hydrogen Ion Carbon dioxide β-alanine α- Ketoisovaleric acid 5,10- Methylene-THF Water Tetrahydrofolic acid 2- dehydropantoate NADPH Hydrogen Ion NADP (R)-pantoate β-Alanine Adenosine triphosphate Adenosine monophosphate Pyrophosphate Hydrogen Ion Pantothenic acid Adenosine triphosphate Adenosine diphosphate Hydrogen Ion D-4'- Phosphopantothenate Cytidine triphosphate L-Cysteine Cytidine monophosphate Pyrophosphate Hydrogen Ion 4'- Phosphopantothenoylcysteine Hydrogen Ion Carbon dioxide 4'- phosphopantetheine Adenosine triphosphate Hydrogen Ion Pyrophosphate Dephospho-CoA Adenosine triphosphate Hydrogen Ion Adenosine diphosphate Coenzyme A Adenosine triphosphate Hydrogen Ion Adenine 2'-(5- Triphosphoribosyl)- 3'-dephospho- CoA 2,3- Dihydroxyisovaleric acid Water Valine Biosynthesis Aspartate Metabolism ilvC