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2,3- dihydroxyphenylpropionate/2,3- dihydroxicinnamic acid 1,2-dioxygenase 2-hydroxy-6- oxononadienedioate/2- hydroxy-6- oxononatrienedioate hydrolase 2-keto-4- pentenoate hydratase 4-hydroxy-2- oxovalerate aldolase Acetaldehyde dehydrogenase Acetolactate synthase isozyme 1 large subunit Acetolactate synthase isozyme 1 small subunit Acetolactate synthase isozyme 2 large subunit Acetolactate synthase isozyme 2 small subunit Acetolactate synthase isozyme 1 large subunit Acetolactate synthase isozyme 1 small subunit Acetolactate synthase isozyme 3 large subunit Acetolactate synthase isozyme 3 small subunit Acetolactate synthase isozyme 3 large subunit Acetolactate synthase isozyme 3 small subunit 2,3- dihydroxyphenylpropionate/2,3- dihydroxicinnamic acid 1,2-dioxygenase 2-hydroxy-6- oxononadienedioate/2- hydroxy-6- oxononatrienedioate hydrolase 3-(3-hydroxy- phenyl)propionate/3- hydroxycinnamic acid hydroxylase 3- phenylpropionate/cinnamic acid dioxygenase ferredoxin subunit 3- phenylpropionate/cinnamic acid dioxygenase ferredoxin-- NAD(+) reductase component 3- phenylpropionate/cinnamic acid dioxygenase subunit beta 3- phenylpropionate/cinnamic acid dioxygenase subunit alpha 3- phenylpropionate- dihydrodiol/cinnamic acid- dihydrodiol dehydrogenase 3-(3-hydroxy- phenyl)propionate/3- hydroxycinnamic acid hydroxylase 2-Hydroxy-3- (4- hydroxyphenyl)propenoic acid O2 H+ 2-Hydroxy-6- ketononatrienedioate H2O H+ Fumaric acid 2-Hydroxy- 2,4- pentadienoate 2-oxopent-4- enoate H2O 4-hydroxy-2- oxopentanoate Pyruvic acid Acetaldehyde CoA NAD H+ NADH Acetyl-CoA CO2 2-Acetolactate 3-(2,3- dihydroxyphenyl)propanoate O2 2-Hydroxy-6- ketononadienedicarboxylate H+ H2O (2Z)-2- hydroxypenta- 2,4-dienoate Succinic acid H+ H+ NADH O2 3-(3- Hydroxyphenyl)propanoic acid H2O NAD trans-Cinnamic acid H+ O2 NADH Cis-3-(3- carboxyethyl)- 3,5- cyclohexadiene- 1,2-diol NAD NAD NADH H+ m-Coumaric acid H+ NADH O2 NAD H2O Fe2+ Fe2+
mhpB mhpC mhpD mhpE mhpF ilvB ilvN ilvG ilvM ilvB ilvN ilvI ilvH ilvI ilvH mhpB mhpC mhpA hcaC hcaD hcaF hcaE hcaB mhpA 2-Hydroxy-3- (4- hydroxyphenyl)propenoic acid Oxygen Hydrogen Ion 2-Hydroxy-6- ketononatrienedioate Water Hydrogen Ion Fumaric acid 2-Hydroxy- 2,4- pentadienoate 2-oxopent-4- enoate Water 4-hydroxy-2- oxopentanoate Pyruvic acid Acetaldehyde Coenzyme A NAD Hydrogen Ion NADH Acetyl-CoA Carbon dioxide 2-Acetolactate 3-(2,3- dihydroxyphenyl)propanoate Oxygen 2-Hydroxy-6- ketononadienedicarboxylate Hydrogen Ion Water (2Z)-2- hydroxypenta- 2,4-dienoate Succinic acid Hydrogen Ion Hydrogen Ion NADH Oxygen 3-(3- Hydroxyphenyl)propanoic acid Water NAD trans-Cinnamic acid Hydrogen Ion Oxygen NADH Cis-3-(3- carboxyethyl)- 3,5- cyclohexadiene- 1,2-diol NAD NAD NADH Hydrogen Ion m-Coumaric acid Hydrogen Ion NADH Oxygen NAD Water